Relativistic Quantum Mechanics: Spin & Dirac Equation

Mathematical Intuition behind Relativistic Quantum Mechanics

This is a course on Relativistic Quantum Mechanics. Why did I create this new course even if there is already a course on Quantum Mechanics and Quantum Field Theory? The answer is simple: the main reason is that I am passionate about these topics, but another reason is the fact that my previous course on QM and QFT already contained roughly 40 hours of content, so it would have been too "chaotic" if I added another 10 hours of content.

Besides, this course is developed on its own (even if we do not start from scratch). In fact, the topics covered here are not covered in the other course. Here we start from some commutation relations regarding angular momentum, from which we derive the concept of spin. It is therefore recommended to have a prerequisite knowledge of operators and commutators, and how the latter are related to the possibility of measuring two physical quantities simultaneously.

After a first part on angular momentum (in particular, intrinsic angular momentum), we use the concepts therein developed to construct the Dirac equation. We will see that the concept of spin is naturally incorporated into the relativistic theory.

Once we have the Dirac equation, we will start solving it in the case of a free particle, and we also derive conserved quantities from it (the Hamiltonian, current, etc.).

From other commutation relations that we derive, we finally find the spectrum of the hydrogen atom in the relativistic case, and compare it with the non-relativistic solution.

Course curriculum

  1. 2
  2. 3
  3. 4
    • Conserved Quantity from the Dirac Equation

  4. 5
    • Non Relativistic Limit of the Dirac Equation part 1

    • Non Relativistic Limit of the Dirac Equation part 2

  5. 6
    • Solution of the Dirac Equation for a Free Particle part 1

    • Solution of the Dirac Equation for a Free Particle part 2 (Particles at Rest)

    • Solution of the Dirac Equation for a Free Particle in the General Case

    • Problem with the Negative Energy Components

    • Interpretation of Negative Energy Solutions

  6. 7
    • Hamiltonian + commutator between Hamiltonian and Total Angular Momentum

    • Hamiltonian and Spin Component along the Total Angular Momentum

    • Commutator between H and K

  7. 8
  8. 9
    • Intro to This Appendix

    • Hydrogen-Like Atoms

    • Hamiltonian of a Hydrogen-Like Atom

    • More on the Potential Energy and How to Find the Spectrum

    • Separation of Variables in the Schrodinger Equation

    • Time Independent Schrodinger Equation in Spherical Coordinates

    • Separating the Variables in the Time-Independent Schrodinger Eq

    • Radial Schrodinger Equation

    • Working on the Radial Schrodinger Equation

    • 9 Solution to the radial Schrodinger equation

    • 10 derivation of the discrete energy spectrum corrected

  9. 10
    • 1 Orbital angular momentum and its square in QM

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    • 2 Laplacian in spherical coordinates

    • 3 Legendre differential equation

    • 4 Solution to the Legendre differential equation

    • 5 Spherical harmonics

    • 6 Eigenfunctions and eigenvalues of Lz and L squared

    • 7 properties of Legendre Polynomials part 1

    • 8 Properties of legendre polynomials part 2: Rodrigues formula

    • 9 Normalization of Legendre polynomials

    • 10 Relation between Beta and Gamma function

    • 11 Completeness relation for the Legendre polynomials

    • 12 Properties of the generalized Legendre polynomials part 1

    • 13 Properties of the generalized Legendre polynomials part 2 : Orthogonality

    • 14 Full formula for the spherical harmonics

    • 15 Symmetry property of spherical harmonics

    • 16 Completeness of spherical harmonics

    • 17 theorem of Addition of Spherical Harmonics

    • 18 Final considerations on the Addition Theorem for Spherical Harmonics

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